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Title: Synthesis of novel α-functionalized phosphinic acid derivatives of thiophene and the first crystal structure of an α-hydroxyalkylphosphinate
Author(s): Bligh, Annie Sim Wan 
Author(s): McPartlin, M.
Sanganee, M. J.
Woodroffe, T. M.
Geraldes, C. F. G. C.
Issue Date: 1998
Publisher: Royal Society of Chemistry
Journal: Chemical Communications 
Issue: 19
Start page: 2073
End page: 2074
Reaction of 2,5-diformylthiophene with Ph2CHNH2 and hypophosphorus acid yields novel α-hydroxy- or α-amino-methylphosphinic acid derivatives depending on reaction conditions; the X-ray structure analysis of diphenylmethylammonium 5-formyl-2-thienyl(hydroxy)methylphosphinate provides the first direct structural information on the α-hydroxyalkylphosphinate class of compounds.
DOI: 10.1039/A805189E
CIHE Affiliated Publication: No
Appears in Collections:HS Publication

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